There isn't enough information to be able to answer your question directly.
It sounds like Acrobat is crashing. Applications crash for all kinds of reasons.
There could be something wrong with one or other of the documents you're trying to merge, so does it happen every single time, with all documents, or only with these two specific documents?
Does it work in other apps? for example Preview has an (somewhat non-obvious) way of merging documents (use view -> Thumbnails to see the pages in your document, then you can drag the thumbnails from the first document into the second document to merge them). If it crashes here then I suspect some issue with the documents in question.
Either way, more information is needed to determine root cause vs. workaround.