When making a drive a Time Machine drive it becomes owned by the Time Machine App and your access to it will be Read Only. Therefore you cannot alter the contents of the Time Machine, only macOS can do that.
Older advice may not apply in this scenario. Time Machine now uses the APFS file system and it's less risky to work with than older file systems. You can actually add an APFS Volume non-destructively and it won't even require being sized. APFS Volumes in the same container share the same free space of all volumes in the container. Just keep in mind you are reducing the total capacity of the Time Machine volume as you add data to the second APFS Volume.
Open Disk Utility and click the View menu and Show All Devices. Locate the Samsung drive on the left-sidebar and highlight the Container on that drive. Right-click and choose Add APFS Volume.
When the disk is attached, you should see two disks mount, each one is an APFS Volume. One of them will be your Time Machine drive that is always Read Only to you. The other new disk is your data drive that you can Read/Write whatever you wish.