You said you're using an HDD formatted ExFAT in a primarily non-FCP application, and you want to know if ExFAT would cause problems in that application. That's difficult to say.
My team uses RED cameras that record to SSD storage formatted as FAT-32. When recording they automatically split the file into approx. 4.16 GB segments. That process is reliable and is handled by FCP provided the RED workflow software is installed. The file segments are presented as a single clip. All other utility software must understand that format to present the RED .R3D file segments as a single logical clip. So that's an example of automatic file segmentation with a well-documented procedure that works well -- at least among utilities that understand the segmentation format.
If you're asking about file management used by some model of Samsung TV recording to some type of FAT 32 portable drive, you'll probably get a better answer from a support source familar with that specific model of TV.
However, I think some TVs also use automatic file segmentation where they split the file to multiple 4 GB segments. I think some TVs will play that back seamlessly, but others might require selecting each file segment. That would probably also require a specific filename convention, such as MOVIE_001.MP4, MOVIE_002.MP4, etc.
You said this was primarily a non-FCP application scenario, but if you're discussing editing or creating a series of file segments with FCP for playback on the Samsung TV, that would require specific technical information from the TV manufacturer.